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- W1967996939 abstract "The kinetics of the reaction of tetracobalt dodecacarbonyl with carbon monoxide to form dicobalt octacarbonyl in n-hexane have been investigated over a wide range of temperature and CO pressure. The reaction is first order in [Co4(CO)12]; the order in [CO] changes between one (at low pressures and high temperatures) and two (at high pressures and low temperatures). Activation parameters have been estimated and a mechanism involving initial reversible breaking of one CoCo bond, followed by irreversible breaking of a second, is proposed. The first step involves concerted addition of CO while the second can proceed with or without such addition." @default.
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- W1967996939 date "1978-07-01" @default.
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- W1967996939 title "Kinetics and mechanism of the reaction of tetracobalt dodecacarbonyl with carbon monoxide under pressure" @default.
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- W1967996939 doi "https://doi.org/10.1016/s0022-328x(00)90869-6" @default.
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