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- W1968047757 abstract "Treatment of N,N‘-dimethyl urea with ClPPh2 and NEt3 as auxiliary base in thf affords the title compound PPh2NMeC(O)NMeH (1) in high yield. The monophosphino urea derivative 1 constitutes the first isolated and fully characterized representative of this class with a NH functional group. Evidence for a solvent effect in the synthesis of 1 is given and the X-ray crystal structure determined. The reaction of 1 with [Mo(CO)4(NCMe)2] and the hemilabile character of the ligand 1 in the obtained P,O-chelate complex cis-[Mo(CO)4(η2-PPh2NMeC(O)NMeH)] (2) are described. Furthermore, synthesis of the known bisphosphino urea derivative CO(NMePPh2)2 (3) starting from 1 is reported." @default.
- W1968047757 created "2016-06-24" @default.
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- W1968047757 date "2002-07-31" @default.
- W1968047757 modified "2023-09-23" @default.
- W1968047757 title "The Monophosphino Urea Derivative PPh<sub>2</sub>NMeC(O)NMeH: A Hemilabile Ligand Switching between P,O- and P,N-Coordination" @default.
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- W1968047757 doi "https://doi.org/10.1021/ic025614e" @default.
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