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- W1968052166 abstract "The identity of a palladium chloronitrosyl complex, active in the catalytic reduction of NO to N2O, has been examined in aqueous and non-aqueous media. Stoichiometry experiments for its formation from [PdCl4]2− show the presence of one bound nitrosyl group per palladium and the requirement of a one-electron reductant, provided by CuCl. Work in non-aqueous solvents identified [Pd2Cl4(NO)2]2− as a key intermediate, although in aqueous 2 M HCl the monomeric form [PdCl3(NO)]2− is suggested to predominate, according to the equilibrium: [Pd2Cl4(NO)2]2− + 2Cl− ⇄[PdCl3(NO)]2−. The [Ph4As]2[Pd2Cl4(NO)2] complex could be oxidized to the stable compound [Ph4As]2[Pd2Cl4(NO)2)2], whose structure was determined by single crystal X-ray diffraction." @default.
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- W1968052166 date "1995-12-01" @default.
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- W1968052166 title "Palladium complexes present during the catalytic reduction of NO to N2O" @default.
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- W1968052166 doi "https://doi.org/10.1016/0020-1693(95)04546-5" @default.
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