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• W1968086871 abstract "Abstract The high temperature species, SiO and AlF, have each been treated with 2,2′-bipyridyl in tetrahydrofuran solution at − 105 °C and in an adamatane matrix at − 196 °C to give products which have spectroscopic properties closely resembling the known compound [SiCl 2 (bipy) 2 ]. When initially formed the products are highly coloured and paramagnetic in solution or in the adamantane matrix and their EPR spectra show the presence of singlet and triplet species. In the triplet species, two electrons are transferred from the silicon or aluminium centre to two bipyridyl ligands which must lie orthogonal to each other across the metal centres but it is uncertain whether the species are monomeric or oligomeric. Evaporation of the solutions causes irreversible precipitation of pyrophoric solids of composition SiO(bipy) or AlF(bipy)." @default.
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• W1968086871 date "1991-11-01" @default.
• W1968086871 modified "2023-10-18" @default.
• W1968086871 title "The reactions of silicon monoxide and aluminium monofluoride with 2,2′-bipyridyl" @default.
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• W1968086871 doi "https://doi.org/10.1016/s0020-1693(00)80187-5" @default.
• W1968086871 hasPublicationYear "1991" @default.
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