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- W1968094788 abstract "The effect of SnSO4 on the deep-discharge capacity of Lead/acid batteries is investigated when it is added to the sulfuric acid electrolyte. The electrochemical behaviour of Sn2+ ions in sulfuric acid is studied by using chemical-analysis and cyclic-voltammetry methods. In the battery system, Sn2+ ions will be reduced to tin on the negative plates or will be oxidized to tin(IV) species on the positive plates. Tin metal formed on the negative plates will improve the chargeJdischarge properties. Tin(IV) species formed on the positive plates may be incorporated as SnO2 in the positive active material (PAM) as well as in the anodic film that is produced at the grid/active-material interface. The effect of SnO2 on the properties of the PAM are explained in terms of the gel-crystal model. The SnO2is stable during the discharge process. The compound increases the electronic conductivity of the gel zones, thereby, enhances the capacity of the PAM. The SnO2 species may also act as nuclei for the formation of β-PbO2 in the crystal zones. The corrosion of positive grids is inhibited by the presence of SnO2. By virtue of these effects, the addition of SnSO4 is beneficial to the operation of lead/acid batteries." @default.
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- W1968094788 date "1994-11-01" @default.
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- W1968094788 title "Electrochemical behaviour of SnSO4 in sulfuric acid solution" @default.
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- W1968094788 doi "https://doi.org/10.1016/0378-7753(94)01936-3" @default.
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