Matches in SemOpenAlex for { <https://semopenalex.org/work/W1968116676> ?p ?o ?g. }
- W1968116676 endingPage "46" @default.
- W1968116676 startingPage "39" @default.
- W1968116676 abstract "The structure and hydrophobic nature of sol–gel mesoporous silica were modified by silylation using trimethylchlorosilane. The efficiency of the process can be enhanced by fine tuning a key sol–gel parameter, the water/precursor molar ratio, thus reducing the amount of silylating agent needed to achieve almost full surface derivatization. It is shown that the modifications imposed by silylation are extensive: the inclusion of the bulky hydrophobic silyl groups does not merely change the chemical nature of the pore walls surface, but induces a deep structural rearrangement of the silica backbone itself, since the pores change in shape and orientation, and the molecular structure has to accommodate the tensions induced by such reorientation. It is possible to tailor simultaneously the hydrophobic properties and the pore morphology of the modified silica by a combined choice of the hydrolysis and silylation ratios." @default.
- W1968116676 created "2016-06-24" @default.
- W1968116676 creator A5042741228 @default.
- W1968116676 creator A5042788556 @default.
- W1968116676 date "2012-08-01" @default.
- W1968116676 modified "2023-10-14" @default.
- W1968116676 title "Tailoring the structure and hydrophobic properties of amorphous silica by silylation" @default.
- W1968116676 cites W1976161821 @default.
- W1968116676 cites W1980704616 @default.
- W1968116676 cites W1988024129 @default.
- W1968116676 cites W2000805335 @default.
- W1968116676 cites W2010699838 @default.
- W1968116676 cites W2011104390 @default.
- W1968116676 cites W2011254969 @default.
- W1968116676 cites W2011762585 @default.
- W1968116676 cites W2013053623 @default.
- W1968116676 cites W2013703981 @default.
- W1968116676 cites W2015430760 @default.
- W1968116676 cites W2025863860 @default.
- W1968116676 cites W2026209669 @default.
- W1968116676 cites W2026586761 @default.
- W1968116676 cites W2039506222 @default.
- W1968116676 cites W2042103404 @default.
- W1968116676 cites W2048386991 @default.
- W1968116676 cites W2055497938 @default.
- W1968116676 cites W2057733562 @default.
- W1968116676 cites W2065011603 @default.
- W1968116676 cites W2069727133 @default.
- W1968116676 cites W2077274830 @default.
- W1968116676 cites W2116014951 @default.
- W1968116676 cites W2164539175 @default.
- W1968116676 cites W2169320013 @default.
- W1968116676 cites W2312199777 @default.
- W1968116676 doi "https://doi.org/10.1016/j.micromeso.2012.03.009" @default.
- W1968116676 hasPublicationYear "2012" @default.
- W1968116676 type Work @default.
- W1968116676 sameAs 1968116676 @default.
- W1968116676 citedByCount "20" @default.
- W1968116676 countsByYear W19681166762013 @default.
- W1968116676 countsByYear W19681166762014 @default.
- W1968116676 countsByYear W19681166762015 @default.
- W1968116676 countsByYear W19681166762016 @default.
- W1968116676 countsByYear W19681166762017 @default.
- W1968116676 countsByYear W19681166762018 @default.
- W1968116676 countsByYear W19681166762020 @default.
- W1968116676 countsByYear W19681166762021 @default.
- W1968116676 countsByYear W19681166762022 @default.
- W1968116676 countsByYear W19681166762023 @default.
- W1968116676 crossrefType "journal-article" @default.
- W1968116676 hasAuthorship W1968116676A5042741228 @default.
- W1968116676 hasAuthorship W1968116676A5042788556 @default.
- W1968116676 hasConcept C118129440 @default.
- W1968116676 hasConcept C127413603 @default.
- W1968116676 hasConcept C161790260 @default.
- W1968116676 hasConcept C178790620 @default.
- W1968116676 hasConcept C179998833 @default.
- W1968116676 hasConcept C185592680 @default.
- W1968116676 hasConcept C188027245 @default.
- W1968116676 hasConcept C192562407 @default.
- W1968116676 hasConcept C2776923573 @default.
- W1968116676 hasConcept C2777496208 @default.
- W1968116676 hasConcept C2993056060 @default.
- W1968116676 hasConcept C42360764 @default.
- W1968116676 hasConcept C5304478 @default.
- W1968116676 hasConcept C56052488 @default.
- W1968116676 hasConcept C82776694 @default.
- W1968116676 hasConcept C90260826 @default.
- W1968116676 hasConcept C94412978 @default.
- W1968116676 hasConceptScore W1968116676C118129440 @default.
- W1968116676 hasConceptScore W1968116676C127413603 @default.
- W1968116676 hasConceptScore W1968116676C161790260 @default.
- W1968116676 hasConceptScore W1968116676C178790620 @default.
- W1968116676 hasConceptScore W1968116676C179998833 @default.
- W1968116676 hasConceptScore W1968116676C185592680 @default.
- W1968116676 hasConceptScore W1968116676C188027245 @default.
- W1968116676 hasConceptScore W1968116676C192562407 @default.
- W1968116676 hasConceptScore W1968116676C2776923573 @default.
- W1968116676 hasConceptScore W1968116676C2777496208 @default.
- W1968116676 hasConceptScore W1968116676C2993056060 @default.
- W1968116676 hasConceptScore W1968116676C42360764 @default.
- W1968116676 hasConceptScore W1968116676C5304478 @default.
- W1968116676 hasConceptScore W1968116676C56052488 @default.
- W1968116676 hasConceptScore W1968116676C82776694 @default.
- W1968116676 hasConceptScore W1968116676C90260826 @default.
- W1968116676 hasConceptScore W1968116676C94412978 @default.
- W1968116676 hasLocation W19681166761 @default.
- W1968116676 hasOpenAccess W1968116676 @default.
- W1968116676 hasPrimaryLocation W19681166761 @default.
- W1968116676 hasRelatedWork W1504519375 @default.
- W1968116676 hasRelatedWork W1997416615 @default.
- W1968116676 hasRelatedWork W2074355424 @default.
- W1968116676 hasRelatedWork W2120704218 @default.
- W1968116676 hasRelatedWork W2161055212 @default.
- W1968116676 hasRelatedWork W2325478899 @default.
- W1968116676 hasRelatedWork W2953196963 @default.
- W1968116676 hasRelatedWork W2966344072 @default.
- W1968116676 hasRelatedWork W4245418064 @default.
- W1968116676 hasRelatedWork W4250052361 @default.