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- W1968163937 abstract "In the presence of 1 mol% octacarbonyl dicobalt ethyl diazoacetate can be transformed at room temperature and carbon monoxide pressure selectively into diethyl 2-diazo-3-oxo-pentanedicarboxylate or in the presence of an alcohol (methanol, ethanol, tert-butanol), phenol or diethylamine into the corresponding malonic acid derivatives in high yields. Ethoxycarbonylcarbene-bridged dicobalt carbonyl complexes [μ2-{ethoxycarbonyl(methylene)}-μ2-(carbonyl)-bis(tricarbonyl-cobalt)(Co–Co)] and [di-μ2(ethoxycarbonyl(methylene)}-bis(tricarbony-cobalt)(Co–Co)] proved to be intermediates in the catalytic reactions." @default.
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- W1968163937 date "2003-09-01" @default.
- W1968163937 modified "2023-10-15" @default.
- W1968163937 title "Octacarbonyl dicobalt-catalyzed selective transformation of ethyl diazoacetate into organic products containing the ethoxycarbonyl carbene building block" @default.
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- W1968163937 doi "https://doi.org/10.1016/s1381-1169(03)00377-7" @default.
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