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• W1968170959 abstract "The synthesis of two carbocyclic guanosine analogues with an electronegative fluoro or hydroxy substituent in the 4-position is described. The cyclopentanols 17a and 18 were synthesized from enantiomerically pure 3S,4S-bis(hydroxymethyl)cyclopentanone ethylene glycol ketal (7) via a number of key steps involving stereospecific reduction of the keto function and a dihydroxylation of the C-4 methylene. Substitution of the tertiary C-4 hydroxyl. group in 16 with fluorine using bis-(2-methoxyethyl)aminosulfur trifluoride (Deoxo-Fluor™) and coupling of the cyclopentanol-moiety with 2-amino-6-chloropurine using the Mitsunobu procedure gave compounds 3 and 4 which have been evaluated as potential anti-viral agents." @default.
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• W1968170959 date "1999-08-01" @default.
• W1968170959 modified "2023-10-16" @default.
• W1968170959 title "Synthesis of 4-substituted carbocyclic 2,3-dideoxy-3-C-hydroxymethyl nucleoside analogues as potential anti-viral agents" @default.
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• W1968170959 doi "https://doi.org/10.1016/s0040-4020(99)00591-8" @default.
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