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- W1968188086 abstract "The abstraction yields from the reaction T + RH ..-->.. HT + R have been measured for a series of haloethylenes under standard conditions in an excess of C/sub 2/D/sub 4/. The tritium atoms have been produced with excess energy from the nuclear reaction /sup 3/He(n,p)T. The order of decreasing HT yield per C-H bond is cis-CHCl=CHCl > cis-CFCl=CHCl > CH/sub 2/ = CH/sub 2/ approx. = CF/sub 2/=CHCl > cis-CHF=CHF approx. = CF/sub 2/=CH/sub 2/ > CF/sub 2/=CHF. The C-H bond dissociation energies of these compounds can be estimated from these yields and range relative to C-H in C/sub 2/H/sub 4/ from -2 kcal/mol, for cis-CHCl=CHCl to +2 kcal/mol for CF/sub 2/=CHF. With the current value of 109 +- 1 kcal/mol for the bond dissociation energy of ethylene, these values for the halothylenes fall in the range from 107 to 111 kcal/mol." @default.
- W1968188086 created "2016-06-24" @default.
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- W1968188086 date "1981-01-01" @default.
- W1968188086 modified "2023-09-24" @default.
- W1968188086 title "Bond dissociation energies of carbon-hydrogen bonds in several haloethylenes, as estimated from the recoil tritium abstraction reaction" @default.
- W1968188086 doi "https://doi.org/10.1021/j150602a006" @default.
- W1968188086 hasPublicationYear "1981" @default.
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