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- W1968233626 endingPage "9682" @default.
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- W1968233626 abstract "New Ru-containing polyoxometalate [PW11O39RuII(NO)]4- (14-) was obtained in high yield by reaction of [Ru(NO)Cl5]2- with [PW11O39]7- and characterized by multinuclear NMR, cyclic voltammetry, IR spectroscopy, and electrospray ionization mass spectrometry (ESI-MS). The intrinsic reactivity of the {RuNO} site in 14- toward various reagents has been studied using a versatile and simple ESI tandem mass spectrometric methodology for identification of the L attached at the Ru site; this approach relies on the preferential liberation of the L ligands attached at the Ru sites upon mass-selecting desired intermediates and subsequent promotion of their fragmentation. Reactions with both hydrazine and hydroxylamine lead to elimination of the nitroso group and quantitative formation of [PW11O39RuIII(H2O)]4- (24-) in aqueous solution. In the reaction with hydroxylamine, an intermediate with coordinated dinitrogen has been detected. An easy access to the NH3-coordinated [PW11O39RuNH3]4- (34-) complex was achieved upon reduction of 14- with Sn2+ in water." @default.
- W1968233626 created "2016-06-24" @default.
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- W1968233626 date "2013-08-07" @default.
- W1968233626 modified "2023-10-16" @default.
- W1968233626 title "New {RuNO} Polyoxometalate [PW<sub>11</sub>O<sub>39</sub>Ru<sup>II</sup>(NO)]<sup>4-</sup>: Synthesis and Reactivity" @default.
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- W1968233626 doi "https://doi.org/10.1021/ic401492q" @default.
- W1968233626 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23924386" @default.
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