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• W1968249957 abstract "The photophysics of 3,3′-diethylthiacarbocyanine iodide (DTCI), as a fluorescence probe, in liquid mixtures of dimethyl sulfoxide (DMSO) with either trimethyl(butyl)ammonium bis((trifluoromethyl)sulfonyl)imide ([N(4)111] [Tf2N]) or 1-butyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide ([bmim] [Tf2N]) was studied by means of steady-state and time resolved fluorescence spectroscopy. The DTCI fluorescence decay was found to be double-exponential in mixtures with [N(4)111] [Tf2N] for DMSO volume fractions less than ca. 0.6 while that is single-exponential in mixtures with [bmim] [Tf2N] under the same conditions. These findings are explained in terms of the Hildebrand solubility model by assuming the existence of coursed-grained spatial micro-heterogeneities in ammonium-based ionic liquid/DMSO mixtures." @default.
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• W1968249957 date "2012-11-01" @default.
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• W1968249957 title "The microheterogeneous structure of ionic liquid mixtures with organic solvent determined by a cyanine-dye fluorescent probe" @default.
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• W1968249957 doi "https://doi.org/10.1016/j.cplett.2012.09.024" @default.
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