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- W1968260077 abstract "Abstract The thermodynamic excess functions for cycloalkane + cycloalkane mixtures have been compared with the predictions of various theories. The use of liquid mechanical properties to determine the pure-fluid parameters offers no advantage over the use of gas-liquid critical constants because the cycloalkanes are approximately conformal. All the theories are satisfactory when the hard-core volumes of the pure components of the mixture are approximately equal, but the theories based on the van der Waals 1-fluid and 2-fluid prescriptions give progressively poorer estimates of VE as the hard-core volume ratio increases. In contrast, the theories of Snider and Herrington and of Gibbons, which are based on a hard-particle mixture equation, and the Flory theory give surprisingly good predictions of the excess volumes." @default.
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- W1968260077 date "1977-09-01" @default.
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- W1968260077 title "Thermodynamics of cycloalkane + cycloalkane mixtures: comparison with theory" @default.
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