Matches in SemOpenAlex for { <https://semopenalex.org/work/W1968273054> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W1968273054 endingPage "270" @default.
- W1968273054 startingPage "261" @default.
- W1968273054 abstract "Abstract Polymerization of acrylonitrile (AN) initiated by Ce4+ isopropyl alcohol (IPA) has been carried out in the presence and absence of Ag+ ions. In the absence of Ag+ ions the order with respect to [IPA], [Ce4+], and [AN] was found to be 0.4, 0.1, and 1.55, respectively. A mechanism involving primary radical production by the reaction of Ce4+ with IPA, which initiates polymerization of AN and mutual termination of growing polymer radicals, is envisaged. In the presence of Ag+ ions the order with respect to [Ag+], [AN], [Ce4+], and [IPA] is found to be 0.4, 1.4, 0.3, and 0.15, respectively. Formation of an Ag+-IPA adduct which is oxidized to radicals by Ce4+ via an intermediate Ag2+ -adduct is assumed. The initiation of polymerization by primary radicals as well as by Ag2+-adduct and mutual termination of growing polymer radicals are proposed to explain the kinetic data." @default.
- W1968273054 created "2016-06-24" @default.
- W1968273054 creator A5013285058 @default.
- W1968273054 creator A5034719349 @default.
- W1968273054 creator A5041448600 @default.
- W1968273054 creator A5076084689 @default.
- W1968273054 date "1982-07-01" @default.
- W1968273054 modified "2023-10-18" @default.
- W1968273054 title "Polymerization of Acrylonitrile Initiated by Ce4+Msopropyl Alcohol Redox System in the Presence and Absence of Ag+: A Kinetic Study" @default.
- W1968273054 cites W1995831923 @default.
- W1968273054 cites W2003267697 @default.
- W1968273054 cites W2050654837 @default.
- W1968273054 cites W2081607214 @default.
- W1968273054 cites W2086691477 @default.
- W1968273054 cites W2091959961 @default.
- W1968273054 cites W2114947027 @default.
- W1968273054 doi "https://doi.org/10.1080/00222338208074423" @default.
- W1968273054 hasPublicationYear "1982" @default.
- W1968273054 type Work @default.
- W1968273054 sameAs 1968273054 @default.
- W1968273054 citedByCount "4" @default.
- W1968273054 countsByYear W19682730542012 @default.
- W1968273054 countsByYear W19682730542020 @default.
- W1968273054 crossrefType "journal-article" @default.
- W1968273054 hasAuthorship W1968273054A5013285058 @default.
- W1968273054 hasAuthorship W1968273054A5034719349 @default.
- W1968273054 hasAuthorship W1968273054A5041448600 @default.
- W1968273054 hasAuthorship W1968273054A5076084689 @default.
- W1968273054 hasConcept C108204754 @default.
- W1968273054 hasConcept C111998727 @default.
- W1968273054 hasConcept C139066938 @default.
- W1968273054 hasConcept C15920480 @default.
- W1968273054 hasConcept C178790620 @default.
- W1968273054 hasConcept C179104552 @default.
- W1968273054 hasConcept C185592680 @default.
- W1968273054 hasConcept C188027245 @default.
- W1968273054 hasConcept C2775850501 @default.
- W1968273054 hasConcept C2778372188 @default.
- W1968273054 hasConcept C2781066024 @default.
- W1968273054 hasConcept C44228677 @default.
- W1968273054 hasConcept C521977710 @default.
- W1968273054 hasConcept C55904794 @default.
- W1968273054 hasConcept C75473681 @default.
- W1968273054 hasConceptScore W1968273054C108204754 @default.
- W1968273054 hasConceptScore W1968273054C111998727 @default.
- W1968273054 hasConceptScore W1968273054C139066938 @default.
- W1968273054 hasConceptScore W1968273054C15920480 @default.
- W1968273054 hasConceptScore W1968273054C178790620 @default.
- W1968273054 hasConceptScore W1968273054C179104552 @default.
- W1968273054 hasConceptScore W1968273054C185592680 @default.
- W1968273054 hasConceptScore W1968273054C188027245 @default.
- W1968273054 hasConceptScore W1968273054C2775850501 @default.
- W1968273054 hasConceptScore W1968273054C2778372188 @default.
- W1968273054 hasConceptScore W1968273054C2781066024 @default.
- W1968273054 hasConceptScore W1968273054C44228677 @default.
- W1968273054 hasConceptScore W1968273054C521977710 @default.
- W1968273054 hasConceptScore W1968273054C55904794 @default.
- W1968273054 hasConceptScore W1968273054C75473681 @default.
- W1968273054 hasIssue "2" @default.
- W1968273054 hasLocation W19682730541 @default.
- W1968273054 hasOpenAccess W1968273054 @default.
- W1968273054 hasPrimaryLocation W19682730541 @default.
- W1968273054 hasRelatedWork W1511138906 @default.
- W1968273054 hasRelatedWork W1986350714 @default.
- W1968273054 hasRelatedWork W2024961918 @default.
- W1968273054 hasRelatedWork W2032097734 @default.
- W1968273054 hasRelatedWork W2058404279 @default.
- W1968273054 hasRelatedWork W2101587685 @default.
- W1968273054 hasRelatedWork W2141400608 @default.
- W1968273054 hasRelatedWork W2204205420 @default.
- W1968273054 hasRelatedWork W2382067821 @default.
- W1968273054 hasRelatedWork W300033535 @default.
- W1968273054 hasVolume "18" @default.
- W1968273054 isParatext "false" @default.
- W1968273054 isRetracted "false" @default.
- W1968273054 magId "1968273054" @default.
- W1968273054 workType "article" @default.