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• W1968287128 abstract "Abstract Cadmium acetate Cd(CH 3 COO) 2 ·2H 2 O and lanthanum nitrate La(NO 3 ) 3 ·6H 2 O were used to prepare the sol in the present investigation. A series of heavy La-doped CdO thin films have been prepared on amorphous glass and single-crystal Si(1 0 0) substrates by sol–gel method. The spin coater technique was employed and the prepared films were pre-annealed at 400 °C. The films were characterised by energy dispersion X-ray fluorescence (EDXRF), X-ray diffraction (XRD), UV–vis-NIR absorption spectroscopy, and dc-electrical measurements. The EDXRF spectrum was used to determine the at.% of La doped into CdO lattice. The structural study by XRD indicates that La 3+ doping grows the CdO lattice parameter due to its relatively larger standard ionic radius, 0.115 nm vs. 0.097 nm for Cd 2+ . It was observed that La-doped film with 27 at.% was growing on Si substrate as an almost single crystal of [1 1 1] orientation. Then, as the doping level increased to 31 at.%, La 2 O 3 nanograins were formed together with La-doped CdO grains. This was explained according to Hume–Rothery (HR) rules and the concept of electronegativity. The electrical measurements indicates that resistivity of crystalline samples grows very strongly with increasing at.% of La doped into CdO structure. The optical absorption studies show that La 3+ in large concentration increases the absorption coefficient in the visible region and widens the bandgap from 2.42 to more than 3 eV." @default.
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• W1968287128 date "2009-01-01" @default.
• W1968287128 modified "2023-10-14" @default.
• W1968287128 title "Structural, electrical, and optical absorption properties of La Cd1−O solid solution films obtained by sol–gel method" @default.
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• W1968287128 doi "https://doi.org/10.1016/j.matchemphys.2008.07.110" @default.
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