Matches in SemOpenAlex for { <https://semopenalex.org/work/W1968291115> ?p ?o ?g. }
- W1968291115 abstract "The real time photodissociation dynamics of CH(3)I from the A band has been studied experimentally and theoretically. Femtosecond pump-probe experiments in combination with velocity map imaging have been carried out to measure the reaction times (clocking) of the different (nonadiabatic) channels of this photodissociation reaction yielding ground and spin-orbit excited states of the I fragment and vibrationless and vibrationally excited (symmetric stretch and umbrella modes) CH(3) fragments. The measured reaction times have been rationalized by means of a wave packet calculation on the available ab initio potential energy surfaces for the system using a reduced dimensionality model. A 40 fs delay time has been found experimentally between the channels yielding vibrationless CH(3)(nu=0) and I((2)P(32)) and I(*)((2)P(12)) that is well reproduced by the calculations. However, the observed reduction in delay time between the I and I(*) channels when the CH(3) fragment appears with one or two quanta of vibrational excitation in the umbrella mode is not well accounted for by the theoretical model." @default.
- W1968291115 created "2016-06-24" @default.
- W1968291115 creator A5035441462 @default.
- W1968291115 creator A5036071135 @default.
- W1968291115 creator A5040796004 @default.
- W1968291115 creator A5042236281 @default.
- W1968291115 creator A5056067251 @default.
- W1968291115 creator A5090935249 @default.
- W1968291115 date "2008-06-26" @default.
- W1968291115 modified "2023-10-18" @default.
- W1968291115 title "A detailed experimental and theoretical study of the femtosecond A-band photodissociation of CH3I" @default.
- W1968291115 cites W1553668733 @default.
- W1968291115 cites W1575653256 @default.
- W1968291115 cites W1663843704 @default.
- W1968291115 cites W1681225665 @default.
- W1968291115 cites W1967875549 @default.
- W1968291115 cites W1972166165 @default.
- W1968291115 cites W1974790898 @default.
- W1968291115 cites W1975703854 @default.
- W1968291115 cites W1986113347 @default.
- W1968291115 cites W1990381963 @default.
- W1968291115 cites W1993566653 @default.
- W1968291115 cites W1993755397 @default.
- W1968291115 cites W2001293558 @default.
- W1968291115 cites W2001374126 @default.
- W1968291115 cites W2002701567 @default.
- W1968291115 cites W2005315955 @default.
- W1968291115 cites W2009538472 @default.
- W1968291115 cites W2010318956 @default.
- W1968291115 cites W2012454287 @default.
- W1968291115 cites W2015710241 @default.
- W1968291115 cites W2016181272 @default.
- W1968291115 cites W2022757366 @default.
- W1968291115 cites W2028742848 @default.
- W1968291115 cites W2030844951 @default.
- W1968291115 cites W2038327849 @default.
- W1968291115 cites W2046775615 @default.
- W1968291115 cites W2047238175 @default.
- W1968291115 cites W2050310104 @default.
- W1968291115 cites W2051949181 @default.
- W1968291115 cites W2053829272 @default.
- W1968291115 cites W2059412749 @default.
- W1968291115 cites W2060788460 @default.
- W1968291115 cites W2063507781 @default.
- W1968291115 cites W2067339297 @default.
- W1968291115 cites W2067791987 @default.
- W1968291115 cites W2067902610 @default.
- W1968291115 cites W2070704887 @default.
- W1968291115 cites W2071062622 @default.
- W1968291115 cites W2071886761 @default.
- W1968291115 cites W2076672366 @default.
- W1968291115 cites W2078953307 @default.
- W1968291115 cites W2079066042 @default.
- W1968291115 cites W2081407315 @default.
- W1968291115 cites W2081869166 @default.
- W1968291115 cites W2085413804 @default.
- W1968291115 cites W2089611318 @default.
- W1968291115 cites W2089904436 @default.
- W1968291115 cites W2089918356 @default.
- W1968291115 cites W2092067215 @default.
- W1968291115 cites W2099883809 @default.
- W1968291115 cites W2118175325 @default.
- W1968291115 cites W2127727822 @default.
- W1968291115 cites W2140051327 @default.
- W1968291115 cites W2147279041 @default.
- W1968291115 cites W2159256376 @default.
- W1968291115 cites W2166603911 @default.
- W1968291115 cites W2168925665 @default.
- W1968291115 cites W2169187187 @default.
- W1968291115 cites W4237059594 @default.
- W1968291115 doi "https://doi.org/10.1063/1.2943198" @default.
- W1968291115 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18601334" @default.
- W1968291115 hasPublicationYear "2008" @default.
- W1968291115 type Work @default.
- W1968291115 sameAs 1968291115 @default.
- W1968291115 citedByCount "90" @default.
- W1968291115 countsByYear W19682911152012 @default.
- W1968291115 countsByYear W19682911152013 @default.
- W1968291115 countsByYear W19682911152014 @default.
- W1968291115 countsByYear W19682911152015 @default.
- W1968291115 countsByYear W19682911152016 @default.
- W1968291115 countsByYear W19682911152017 @default.
- W1968291115 countsByYear W19682911152018 @default.
- W1968291115 countsByYear W19682911152019 @default.
- W1968291115 countsByYear W19682911152020 @default.
- W1968291115 countsByYear W19682911152021 @default.
- W1968291115 countsByYear W19682911152022 @default.
- W1968291115 countsByYear W19682911152023 @default.
- W1968291115 crossrefType "journal-article" @default.
- W1968291115 hasAuthorship W1968291115A5035441462 @default.
- W1968291115 hasAuthorship W1968291115A5036071135 @default.
- W1968291115 hasAuthorship W1968291115A5040796004 @default.
- W1968291115 hasAuthorship W1968291115A5042236281 @default.
- W1968291115 hasAuthorship W1968291115A5056067251 @default.
- W1968291115 hasAuthorship W1968291115A5090935249 @default.
- W1968291115 hasBestOaLocation W19682911152 @default.
- W1968291115 hasConcept C106978608 @default.
- W1968291115 hasConcept C120665830 @default.
- W1968291115 hasConcept C121332964 @default.
- W1968291115 hasConcept C125277925 @default.