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- W1968291489 abstract "Typically, reduction of column temperature increases the enantioselectivity of a chiral stationary phase. An instance in which progressive reduction of temperature initially reduces enantioselectivity, then inverts the elution order of the enantiomers, and finally causes enantioselectivity to increase has been observed. This behavior is related to the nature and concentration of the polar modifier in the mobile phase, and requires particular chiral phase-analyte-mobile phase combinations. A rationalization is presented as to the possible origin of this behavior. This rationale may aid in finding other examples of this temperature-dependent elution order of enantiomers and ultimately increase our understanding of chiral recognition processes." @default.
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- W1968291489 date "1993-05-01" @default.
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- W1968291489 title "An instance of temperature-dependent elution order of enantiomers from a chiral brush-type HPLC column" @default.
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- W1968291489 doi "https://doi.org/10.1002/jhrc.1240160505" @default.
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