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• W1968308132 abstract "As in SiO 2 which, at high pressures, undergoes the α-quartz → stishovite transition, GaAsO 4 transforms into a dirutile structure at 9 GPa and 1173 K. In 2002, a new GaAsO 4 polymorph was found by quenching the compound from 6 GPa and 1273 K to ambient conditions. The powder diagram was indexed on the basis of a hexagonal cell ( a = 8.2033, c = 4.3941 Å, V = 256.08 Å 3 ), but the structure did not correspond to any known structure of other AX O 4 compounds. We report here the ab initio crystal structure determination of this hexagonal polymorph from powder data. The new phase is isostructural to β-MnSb 2 O 6 and it can be described as a lacunary derivative of NiAs with half the octahedral sites being vacant, but it also contains fragments of the rutile-like structure." @default.
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• W1968308132 date "2006-11-14" @default.
• W1968308132 modified "2023-09-27" @default.
• W1968308132 title "Structural characterization of a new high-pressure phase of GaAsO₄" @default.
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• W1968308132 doi "https://doi.org/10.1107/s0108768106039760" @default.
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