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- W1968342194 abstract "The crystal structures of PdCl2[(−)-DIOP], PtCl2[(−)-DIOP] and of NiCl2-[(−)-DIOP] have been determined by X-ray analysis and refined by least-squares methods [(−)-DIOP=(−)-2,2-dimethyl-4,5-bis(diphenylphosphinomethyl)-1,3-dioxolane]. The coordination around the nickel atom is tetrahedral, the coordination around palladium and platinum is square planar. The unit cell of the palladium complex contains two non-equivalent molecules with different conformations of the seven-membered chelate ring involving the metal and the two phosphorus atoms. PtCl2[(−)-DIOP] is isostructural with the corresponding palladium complex." @default.
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- W1968342194 date "1979-06-08" @default.
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- W1968342194 title "Crystal Structures of the (?)-DIOP Complexes of Nickel, Palladium and Platinum Dichloride" @default.
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- W1968342194 doi "https://doi.org/10.1002/hlca.19790620412" @default.
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