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- W1968378683 abstract "Cyclotrimerization of triynes branched by a nitrogen atom of 2-aminophenol yielded planar-chiral tripodal cage compounds. When a cationic Rh−Me-DUPHOS catalyst was used, the cycloadducts were obtained in high yield and excellent ee, and a macrocyclic compound with a [15]cyclophane system was also obtained. This method can be further applied to the synthesis of a triarmed pyridinophane by the intramolecular reaction of a diyne−nitrile." @default.
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- W1968378683 date "2009-08-10" @default.
- W1968378683 modified "2023-10-18" @default.
- W1968378683 title "Enantioselective Synthesis of Chiral Tripodal Cage Compounds by [2 + 2 + 2] Cycloaddition of Branched Triynes" @default.
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- W1968378683 doi "https://doi.org/10.1021/ol9014893" @default.
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