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• W1968390667 abstract "We argue on the basis of symmetry selection rules and Raman scattering spectra that NaV$_2$O$_5$ undergoes a charge ordering phase transition at T$_c$=34 K. Such a transition is characterized by the redistribution of the charges at the phase transition and corresponds to the change of the vanadium ions, from uniform V$^{4.5+}$ to two different V$^{4+}$ and V$^{5+}$ states. In the low temperature phase the V$^{4+}$ ions are forming a zig-zag ladder structure along the {bf b}-axis, consistent with the symmetry of the P2/b space group." @default.
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• W1968390667 date "1999-10-01" @default.
• W1968390667 modified "2023-10-18" @default.
• W1968390667 title "First evidence for charge ordering in NaV2O5 from Raman spectroscopy" @default.
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• W1968390667 doi "https://doi.org/10.1016/s0038-1098(99)00338-5" @default.
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