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- W1968419040 abstract "We study charge delocalization and polarization effects in organic thin films by comparing surface- and bulk-sensitive, high-resolution $mathrm{C}phantom{rule{0.2em}{0ex}}1mathrm{s}$ photoemission data using tunable synchrotron radiation. In three cases, perylene-tetracarboxylicacid-dianhydride, coronene, and metal-free phthalocyanine, no surface core level shifts are observed (upper limit $100phantom{rule{0.3em}{0ex}}mathrm{meV}$). This unexpected finding shows that polarization effects, and hence polarization differences between surface and bulk, are rather small, and implies that the effective charge is not localized on the core-ionized molecule but delocalized over several neighboring molecules." @default.
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- W1968419040 date "2007-11-26" @default.
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- W1968419040 title "Investigation of polarization effects in organic thin films by surface core-level shifts" @default.
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- W1968419040 doi "https://doi.org/10.1103/physrevb.76.193311" @default.
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