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- W1968468520 abstract "We propose X-ray absorption (XAS) measurements as a novel approach to determine the atomic structure of pre-Guinier–Preston zones. These nano-clusters are formed during very early stages of aging AlCu alloys, immediately after solution heat treatment and quenching. X-ray absorption near-edge structure (XANES) spectra were taken from technical aluminum alloys at the copper K edge, revealing the local atomic environment of copper. The spectra of – after solution heat treatment – freshly quenched and of artificially aged alloys differ significantly from each other. We compare the measured XANES spectra with those calculated by the FEFF-8 code. We show the importance of employing realistic, i.e. relaxed, atomic coordinates around the scattering atom type from ab-initio calculations with SIESTA. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)" @default.
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- W1968468520 date "2007-10-01" @default.
- W1968468520 modified "2023-09-26" @default.
- W1968468520 title "Atomic structure of pre-Guinier–Preston zones in Al alloys" @default.
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- W1968468520 doi "https://doi.org/10.1002/pssr.200701090" @default.
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