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- W1968471566 abstract "Perfluoroalkylation of electron-rich aromatic compounds with trifluoromethyl bromide, or long-chain perfluoroalkyl iodides, was performed in the presence of sodium dithionite or zinc–sulphur dioxide. This alkylation occurred at the ortho and para positions relative to the amino or hydroxy substituent. Pyrroles were perfluoroalkylated regioselectively at the 2-position. This alkylation was interpreted as a radical aromatic substitution; the formation of the perfluoroalkyl radical can be induced by a single-electron transfer from sulphur dioxide radical anion to the perfluoroalkyl halide." @default.
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- W1968471566 date "1990-01-01" @default.
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- W1968471566 title "Reactions of trifluoromethyl bromide and related halides: part 10. Perfluoroalkylation of aromatic compounds induced by sulphur dioxide radical anion precursors" @default.
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- W1968471566 doi "https://doi.org/10.1039/p19900002293" @default.
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