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- W1968472783 abstract "The vSN vibration is analyzed for seven N-(2,4,6-trichlorophenyl) substituted imidosulfites, i.e. five 6-membered ring, one 8-membered ring and the dimethyl-imidosulfite. It is used for the determination of the spatial arrangement of the imidosulfite moiety as well as the rotational isomerism around the SN bond. In the absence of steric hindrance, the anti rotamer vs. sulfur atom lone pair is found the most stable as confirmed by ab initio calculations on model structures and by X-ray diffraction measurements. Trimethylene imidosulfite exists as an equilibrium between two inverted chairs forms (ΔG = 0.92 kJ mol−1) and dimethylimidosulfite as a twist-like conformation." @default.
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- W1968472783 date "1983-01-01" @default.
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- W1968472783 title "Use of the SN stretching vibration as a conformational probe. Stereochemistry of the imidosulfite group and rotational isomerism around the SN bond" @default.
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- W1968472783 doi "https://doi.org/10.1016/0584-8539(83)80082-8" @default.
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