Matches in SemOpenAlex for { <https://semopenalex.org/work/W1968475055> ?p ?o ?g. }
- W1968475055 endingPage "1223" @default.
- W1968475055 startingPage "1217" @default.
- W1968475055 abstract "Abstract magnified image An efficient and stereoselective protocol for the preparation of β,β‐disubstituted acrylates in good to high yields by means of a Heck–Matsuda arylation was accomplished. The method employs a base‐ and ligand‐free Heck arylation reaction of methyl cinnamate using both electron‐deficient and electron‐rich arenediazonium salts as electrophiles. The Heck reaction displays a remarkable electronic dependence regarding the diastereoselectivity of the arylation process, which correlates with the electronic nature of the arenediazonium salts employed. A rationale for the observed diastereoselectivity is presented. The overall methodology provides a convenient route to 3‐arylindanones and 4‐aryltetralones allowing the concise formal total syntheses of the therapeutically important psychoactive compounds (±)‐indatraline and (±)‐sertraline." @default.
- W1968475055 created "2016-06-24" @default.
- W1968475055 creator A5051677904 @default.
- W1968475055 creator A5077908365 @default.
- W1968475055 date "2009-06-01" @default.
- W1968475055 modified "2023-10-18" @default.
- W1968475055 title "Remarkable Electronic Effect on the Diastereoselectivity of the Heck Reaction of Methyl Cinnamate with Arenediazonium Salts: Formal Total Synthesis of (±)‐Indatraline and (±)‐Sertraline" @default.
- W1968475055 cites W1561311795 @default.
- W1968475055 cites W1965399992 @default.
- W1968475055 cites W1965929964 @default.
- W1968475055 cites W1966363887 @default.
- W1968475055 cites W1966368315 @default.
- W1968475055 cites W1968514888 @default.
- W1968475055 cites W1969470048 @default.
- W1968475055 cites W1973051136 @default.
- W1968475055 cites W1976307562 @default.
- W1968475055 cites W1981754097 @default.
- W1968475055 cites W1984950344 @default.
- W1968475055 cites W1985042246 @default.
- W1968475055 cites W1985768828 @default.
- W1968475055 cites W1999685593 @default.
- W1968475055 cites W2004140908 @default.
- W1968475055 cites W2004262991 @default.
- W1968475055 cites W2005836734 @default.
- W1968475055 cites W2012394473 @default.
- W1968475055 cites W2012982034 @default.
- W1968475055 cites W2014833129 @default.
- W1968475055 cites W2016757577 @default.
- W1968475055 cites W2024752439 @default.
- W1968475055 cites W2025367875 @default.
- W1968475055 cites W2026841657 @default.
- W1968475055 cites W2028172568 @default.
- W1968475055 cites W2031837588 @default.
- W1968475055 cites W2050288389 @default.
- W1968475055 cites W2053469911 @default.
- W1968475055 cites W2056339662 @default.
- W1968475055 cites W2063545353 @default.
- W1968475055 cites W2065818082 @default.
- W1968475055 cites W2067786669 @default.
- W1968475055 cites W2078771835 @default.
- W1968475055 cites W2100372061 @default.
- W1968475055 cites W2107751342 @default.
- W1968475055 cites W2128861746 @default.
- W1968475055 cites W2135193488 @default.
- W1968475055 cites W2135871575 @default.
- W1968475055 cites W2138900543 @default.
- W1968475055 cites W2141303780 @default.
- W1968475055 cites W2141453896 @default.
- W1968475055 cites W2155431429 @default.
- W1968475055 cites W2163282433 @default.
- W1968475055 cites W2171188278 @default.
- W1968475055 cites W2318665605 @default.
- W1968475055 cites W2326288905 @default.
- W1968475055 cites W2483190452 @default.
- W1968475055 cites W2949388375 @default.
- W1968475055 cites W2949755169 @default.
- W1968475055 cites W2949770646 @default.
- W1968475055 cites W2949994121 @default.
- W1968475055 cites W2950042323 @default.
- W1968475055 cites W2950672696 @default.
- W1968475055 cites W2950750941 @default.
- W1968475055 cites W2951121299 @default.
- W1968475055 cites W2951513946 @default.
- W1968475055 cites W2951688191 @default.
- W1968475055 cites W2951822872 @default.
- W1968475055 cites W2952037148 @default.
- W1968475055 cites W2952158799 @default.
- W1968475055 cites W2952322357 @default.
- W1968475055 cites W2953290320 @default.
- W1968475055 cites W4231464160 @default.
- W1968475055 cites W4233000756 @default.
- W1968475055 cites W4237056151 @default.
- W1968475055 cites W653153694 @default.
- W1968475055 doi "https://doi.org/10.1002/adsc.200900032" @default.
- W1968475055 hasPublicationYear "2009" @default.
- W1968475055 type Work @default.
- W1968475055 sameAs 1968475055 @default.
- W1968475055 citedByCount "59" @default.
- W1968475055 countsByYear W19684750552012 @default.
- W1968475055 countsByYear W19684750552013 @default.
- W1968475055 countsByYear W19684750552014 @default.
- W1968475055 countsByYear W19684750552015 @default.
- W1968475055 countsByYear W19684750552016 @default.
- W1968475055 countsByYear W19684750552017 @default.
- W1968475055 countsByYear W19684750552018 @default.
- W1968475055 countsByYear W19684750552020 @default.
- W1968475055 countsByYear W19684750552021 @default.
- W1968475055 countsByYear W19684750552022 @default.
- W1968475055 crossrefType "journal-article" @default.
- W1968475055 hasAuthorship W1968475055A5051677904 @default.
- W1968475055 hasAuthorship W1968475055A5077908365 @default.
- W1968475055 hasConcept C116569031 @default.
- W1968475055 hasConcept C161790260 @default.
- W1968475055 hasConcept C168896768 @default.
- W1968475055 hasConcept C170493617 @default.
- W1968475055 hasConcept C178790620 @default.
- W1968475055 hasConcept C181647583 @default.
- W1968475055 hasConcept C185592680 @default.