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• W1968486630 endingPage "3873" @default.
• W1968486630 startingPage "3873" @default.
• W1968486630 abstract "1,2,3-Benzodithiazolyl, 2,1,3-benzothiaselenazolyl and 1,2,3-benzodiselenazolyl radicals were generated by the reduction of the corresponding cations and investigated by pulse EPR and ENDOR in frozen CHCl(3) solutions at 30 and 80 K. These methods, in combination with density functional theory calculations, were used to study the magnetic parameters of the radicals, namely the principal values of the nitrogen and proton hyperfine interactions and g-tensors. The spin density distribution was shown to be nearly the same for all investigated radicals and, therefore, replacement of sulfur by selenium leads to a limited perturbation of the radicals' electronic structure. A high anisotropy of the g-tensors was found for the selenium-containing radicals." @default.
• W1968486630 created "2016-06-24" @default.
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• W1968486630 date "2011-01-01" @default.
• W1968486630 modified "2023-09-25" @default.
• W1968486630 title "Pulse EPR and ENDOR study of 1,2,3-benzodithiazolyl, 2,1,3-benzothiaselenazolyl and 1,2,3-benzodiselenazolyl radicals" @default.
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• W1968486630 doi "https://doi.org/10.1039/c0cp02051f" @default.
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