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- W1968520070 abstract "Dichlorobis[(4S,7R)-7,8,8-trimethyl-4,5,6,7-tetrahydro-4,7-methano-2H-in-dazole]copper(II), C22H32Cl2N4Cu, crystallizes in the monoclinic space group C2 with a = 23.110(5), b = 7.533(1), c = 7.041(1) Å, β = 105.25(2)° and Z = 2. The structure was refined to R = 2.9%. The copper atom lies on a crystallographic two-fold rotation axis and has coordination geometry intermediate between tetrahedral and square-planar. A system of bifurcated (intra- and intermolecular) NH ⋯Cl hydrogen bonds connects the molecules in chains. The crystal structure and NMR studies of a palladium(II) complex show that the title ligand complexes through the more sterically hindered N(1) nitrogen. It is proposed that for unsymmetrical pyrazoles, the relative stabilities of the tautomers of the ligand is an important factor in determining the choice of the siteof coordination to metal ions." @default.
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- W1968520070 date "1989-01-01" @default.
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- W1968520070 title "Chiral heterocyclic ligandsVI. (4S,7R)-7,8,8-trimethyl-4,5,6,7-tetrahydro-4,7-methano-1H(2H)-indazole and X-ray structure of a copper(II) complex" @default.
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- W1968520070 doi "https://doi.org/10.1016/s0277-5387(00)86534-1" @default.
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