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- W1968530006 abstract "Optical observation under the polarizing microscope and DSC measurements on K3H(SeO4)2 single crystal have been carried out in the temperature range 25–200 °C. It reveals a high-temperature structural phase transition at around 110 °C. The crystal system transformed from monoclinic to trigonal. Electrical impedance measurements of K3H(SeO4)2 were performed as a function of both temperature and frequency. The electrical conduction and dielectric relaxation have been studied. The temperature dependence of electrical conductivity indicates that the sample crystal became a fast ionic conductor in the high-temperature phase. The frequency dependence of conductivity follows the Jonscher's universal dynamic law with the relation σ(ω)=σ(0)+Aωn, where ω is the frequency of the AC field, and n is the exponent. The obtained n values decrease from 1.2 to 0.1 from the room temperature phase to fast ionic phase. The high ionic conductivity in the high-temperature phase is explained by the dynamical disordering of protons between the neighboring SeO4 groups, which provide more vacant sites in the crystal." @default.
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- W1968530006 date "2002-11-01" @default.
- W1968530006 modified "2023-10-06" @default.
- W1968530006 title "Dielectric and AC ionic conductivity investigations in K 3 H(SeO 4 ) 2 single crystal" @default.
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- W1968530006 doi "https://doi.org/10.1016/s0022-3697(02)00196-8" @default.
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