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- W1968541435 abstract "Abstract Glass transition temperature Tg, specific volume v and viscosity n were measured for two homologous series of oligomer fractions having the same linear perfluorinated poly(oxymethyleneco-oxyethylene) molecular body, and a pair of equal end units -CH2OH or -CH2OCOCF3. By decreasing the molecular weight a marked end unit effect is observed in a progressively differing value of every property of the two series. Typical two-parameter equations are valid, to a first approximation, to represent Tg -M and v-M relations, whereas the diol series shows a remarkably anomalous, non-monotonic trend of the n-M relation, which does not follow the typical exponential equation below Mc, as does on the contrary the trifluoroacetate series." @default.
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- W1968541435 date "1994-05-01" @default.
- W1968541435 modified "2023-09-23" @default.
- W1968541435 title "Some physical properties of two homologous series of perfluoro-polyoxyalkylene oligomers" @default.
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- W1968541435 doi "https://doi.org/10.1016/0014-3057(94)90075-2" @default.
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