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• W1968555788 abstract "The ability of low molecular weight amides to support amphiphile self-assembly is shown to be a general feature for this class of solvents. This report extends the number of known polar solvents which can support amphiphile self-assembly by five new amides; more than doubling the number of known amides able to serve as amphiphile self-assembly media. The formation of lyotropic liquid crystalline phases by cationic and non-ionic surfactants in these liquid amides is reported. The ability of a solvent to promote amphiphile self-assembly is governed by the solvophobic effect and is linked to the solvent cohesiveness. The Gordon parameter which is a measure of the solvent cohesiveness was found to provide a guide to an amides capacity to support lyotropic liquid crystalline phase diversity and thermal stability ranges of those phases. The solvophobic effect and steric hindrance factors were compared between amide's and protic ionic liquids possessing analogous chemical structures and also being able to promote amphiphile self-assembly." @default.
• W1968555788 created "2016-06-24" @default.
• W1968555788 creator A5050696191 @default.
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• W1968555788 date "2011-01-01" @default.
• W1968555788 modified "2023-10-17" @default.
• W1968555788 title "Nanostructure and amphiphile self-assembly in polar molecular solvents: amides and the “solvophobic effect”" @default.
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• W1968555788 doi "https://doi.org/10.1039/c1cp20481e" @default.
• W1968555788 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21468392" @default.
• W1968555788 hasPublicationYear "2011" @default.
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