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- W1968556600 abstract "Treatment of 1,3-dialkyl-2-(phenylthio)benzimidazolium salts 3 and 1,3-dialkyl-2-phenylthio-1H-imidazolium salts 7 with aq. K2CO3 gives 1,3-dialkyl-1,3-dihydrobenzimidazol-2-ones 4 and 1,3-dialkyl-1,3-dihydroimidazol-2-ones 8, respectively, in 22–94% yield. A regio-isomer 17 of kealiiquinone, a marine benzimidazole alkaloid, where the 4-methoxyphenyl group at the 4-position migrates to the 9-position, is synthesized by application of the reaction. Cytotoxity of 17 and kealiiquinone against 39 human cancer cells is evaluated. They have weak activity but a unique mechanism of action." @default.
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- W1968556600 date "2001-01-01" @default.
- W1968556600 modified "2023-10-02" @default.
- W1968556600 title "Synthesis of a regio-isomer of kealiiquinone, a marine benzimidazole alkaloid" @default.
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- W1968556600 doi "https://doi.org/10.1039/b007560o" @default.
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