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• W1968565516 abstract "The dielectric properties and microstructure of magnesium-doped Ba1+k(Ti1−xCax)O3−x+k ceramics have been investigated. When Ba1+k(Ti1−xCax)O3−x+k ceramics, 0≤x≤0.02, 0≤k≤0.01, sintered in pure nitrogen, it behaves as undoped barium titanate. In this study, microstructure, electrical resistivity and dielectric characteristics of magnesium-doped Ba1+k(Ti1−xCax)O3−x+k ceramics with various k and x value and magnesium concentration are studied systematically. Moreover, the effects of Ba/Ti ratio on microstructure and dielectric properties were studied. The results show that Magnesium-doped Ba1+k(Ti1−xCax)O3−x+k was more difficult to sinter than ceramic Ba1+k(Ti1−xCax)O3−x+k. Ca and Mg co-doped BaTiO3 has the poorest electrical resistivity properties compared to Ca- or Mg-doped BaTiO3. When temperature is higher than 100 °C, the curve of temperature dependence of dielectric loss warps upwards markedly, which is caused by migration of oxygen vacancies. Ba/Ti ratio had an important impact on the Curie temperature." @default.
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• W1968565516 date "2004-01-01" @default.
• W1968565516 modified "2023-09-25" @default.
• W1968565516 title "Dielectric properties and microstructure of magnesium-doped Ba1+k(Ti1−xCax)O3−x+k ceramics" @default.
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• W1968565516 doi "https://doi.org/10.1016/j.ceramint.2003.12.036" @default.
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