FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1968584612> ?p ?o ?g. }

• W1968584612 endingPage "1729" @default.
• W1968584612 startingPage "1717" @default.
• W1968584612 abstract "In the gas phase, the doubly-charged ions of small molecules (molecular dications) exhibit a wide range of reactivity following bimolecular collisions with neutral species. This feature article presents an overview of what is known of this reactivity, and presents a detailed discussion of the dynamics of some of those reactions that involve making and breaking chemical bonds. The article also presents recent results from a new position-sensitive coincidence spectrometer designed to study the dynamics of dication reactions by detecting, in coincidence, the pair of monocations often formed in such processes. Detecting the pair of product ions in coincidence from an individual reactive event, using a time-of-flight mass spectrometer equipped with a position sensitive detector, allows their initial velocity vectors to be determined. Experiments studying the electron transfer reactions of atomic dications illustrate the feasibility of this coincidence technique and scattering diagrams obtained from studies of the Ne2+ + Ar collision system are presented. The coincidence technique is particularly suited for the study of reactions which produce three products. For such three-body reactions the coincidence experiment, unlike conventional techniques, allows the initial velocity vectors of all three products to be determined for each reactive event. Illustrative results show that the dissociative electron transfer reaction of CF32+ with Ar proceeds sequentially via the dissociation of highly excited vibrational levels of the electronic ground state of CF3+. In addition, the formation of OCF+ following collisions of CF22+ with H2O proceeds via a long-lived collision complex which decays via charge-separation to form a proton and HF-OCF+. The molecular monocation then dissociates to yield OCF+ and HF." @default.
• W1968584612 created "2016-06-24" @default.
• W1968584612 creator A5036343437 @default.
• W1968584612 date "2003-04-02" @default.
• W1968584612 modified "2023-09-26" @default.
• W1968584612 title "Investigating the gas-phase chemical reactions of molecular dications" @default.
• W1968584612 cites W1480859092 @default.
• W1968584612 cites W1492856624 @default.
• W1968584612 cites W1553691261 @default.
• W1968584612 cites W1553817525 @default.
• W1968584612 cites W1622070452 @default.
• W1968584612 cites W1966136249 @default.
• W1968584612 cites W1974058001 @default.
• W1968584612 cites W1974821647 @default.
• W1968584612 cites W1974861277 @default.
• W1968584612 cites W1974961228 @default.
• W1968584612 cites W1976233621 @default.
• W1968584612 cites W1977222399 @default.
• W1968584612 cites W1979277059 @default.
• W1968584612 cites W1979778225 @default.
• W1968584612 cites W1982945957 @default.
• W1968584612 cites W1984718851 @default.
• W1968584612 cites W1988828258 @default.
• W1968584612 cites W1995160174 @default.
• W1968584612 cites W1995623021 @default.
• W1968584612 cites W2000763250 @default.
• W1968584612 cites W2001965767 @default.
• W1968584612 cites W2005822154 @default.
• W1968584612 cites W2006665783 @default.
• W1968584612 cites W2008332498 @default.
• W1968584612 cites W2009053049 @default.
• W1968584612 cites W2010337848 @default.
• W1968584612 cites W2013817303 @default.
• W1968584612 cites W2014493887 @default.
• W1968584612 cites W2016405314 @default.
• W1968584612 cites W2016602834 @default.
• W1968584612 cites W2017689937 @default.
• W1968584612 cites W2018312077 @default.
• W1968584612 cites W2019157714 @default.
• W1968584612 cites W2025894866 @default.
• W1968584612 cites W2026515304 @default.
• W1968584612 cites W2027910493 @default.
• W1968584612 cites W2028775760 @default.
• W1968584612 cites W2029367560 @default.
• W1968584612 cites W2029503536 @default.
• W1968584612 cites W2033688800 @default.
• W1968584612 cites W2034107933 @default.
• W1968584612 cites W2037197694 @default.
• W1968584612 cites W2038308360 @default.
• W1968584612 cites W2038464038 @default.
• W1968584612 cites W2038722397 @default.
• W1968584612 cites W2038855945 @default.
• W1968584612 cites W2040251712 @default.
• W1968584612 cites W2041203349 @default.
• W1968584612 cites W2049852177 @default.
• W1968584612 cites W2051231569 @default.
• W1968584612 cites W2052751013 @default.
• W1968584612 cites W2058933613 @default.
• W1968584612 cites W2059123793 @default.
• W1968584612 cites W2061389250 @default.
• W1968584612 cites W2063951840 @default.
• W1968584612 cites W2064410062 @default.
• W1968584612 cites W2065108234 @default.
• W1968584612 cites W2068944517 @default.
• W1968584612 cites W2070200066 @default.
• W1968584612 cites W2070293602 @default.
• W1968584612 cites W2073489243 @default.
• W1968584612 cites W2074518306 @default.
• W1968584612 cites W2077673115 @default.
• W1968584612 cites W2078055010 @default.
• W1968584612 cites W2078367583 @default.
• W1968584612 cites W2083453511 @default.
• W1968584612 cites W2085372626 @default.
• W1968584612 cites W2089842989 @default.
• W1968584612 cites W2091312712 @default.
• W1968584612 cites W2092591169 @default.
• W1968584612 cites W2106643434 @default.
• W1968584612 cites W2135494969 @default.
• W1968584612 cites W2149037369 @default.
• W1968584612 cites W2151415814 @default.
• W1968584612 cites W2162600988 @default.
• W1968584612 cites W2264557612 @default.
• W1968584612 cites W2469087981 @default.
• W1968584612 doi "https://doi.org/10.1039/b301957h" @default.
• W1968584612 hasPublicationYear "2003" @default.
• W1968584612 type Work @default.
• W1968584612 sameAs 1968584612 @default.
• W1968584612 citedByCount "95" @default.
• W1968584612 countsByYear W19685846122012 @default.
• W1968584612 countsByYear W19685846122013 @default.
• W1968584612 countsByYear W19685846122014 @default.
• W1968584612 countsByYear W19685846122015 @default.
• W1968584612 countsByYear W19685846122016 @default.
• W1968584612 countsByYear W19685846122017 @default.
• W1968584612 countsByYear W19685846122018 @default.
• W1968584612 countsByYear W19685846122020 @default.
• W1968584612 countsByYear W19685846122021 @default.
• W1968584612 countsByYear W19685846122022 @default.

• next