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- W1968585986 abstract "The rate constants for oxygen quenching in benzene solution of the triplet states of several organic compounds with relatively high triplet energies have been measured in laser photolysis and pulse radiolysis experiments. The previously observed trend for aromatic hydrocarbons where the quenching rate constants decrease from a limiting value of about one ninth of that expected for a diffusion controlled reaction to lower values for triplet states with increasing triplet energy was not observed for the triplet states of certain aromatic ketones and amines. The higher rate constants observed, e.g. oxygen quenching of triplet N-methyl indole has kQ = 1.4 × 1010 dm3 mol−1 s−1, are interpreted as being due to the presence of low lying triplet charge-transfer states which enhance the efficiency of quenching." @default.
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- W1968585986 date "1977-02-01" @default.
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- W1968585986 title "Quenching of triplet states by molecular oxygen and the role of charge-transfer interactions" @default.
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- W1968585986 doi "https://doi.org/10.1016/0009-2614(77)80057-2" @default.
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