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- W1968596140 abstract "Infrared spectroscopy has been used to investigate the complexes that are formed when acids are evaporated onto goethite. It is probable that, like HPO2−4, the anions SO2−4, SeO2−3, and oxalate are adsorbed by ligand exchange and form binuclear bridging complexes where two singly coordinated A-type OH groups are replaced by two oxygen atoms of one ligand. There is evidence that HPO2−4 and oxalate are likely to be present in this form in wet environments, and this is probably also true for SO2−4 and SeO2−3. Fluoride ions can completely replace the singly coordinated A-type OH groups but do not replace C- or B-type OH groups that are coordinated, respectively, to two and three Fe3+ ions. The other halides, nitrate, and benzoate partially replace the A-type OH groups, benzoate being adsorbed as a monodentate ligand. Copper ions do not appear to react with A-type OH but zinc ions are probably adsorbed on the goethite (100) face in conjunction with carbonate or bicarbonate." @default.
- W1968596140 created "2016-06-24" @default.
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- W1968596140 date "1977-06-01" @default.
- W1968596140 modified "2023-10-11" @default.
- W1968596140 title "ADSORPTION ON HYDROUS OXIDES. IV. MECHANISMS OF ADSORPTION OF VARIOUS IONS ON GOETHITE" @default.
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- W1968596140 doi "https://doi.org/10.1111/j.1365-2389.1977.tb02238.x" @default.
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