FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W196860712> ?p ?o ?g. }

• W196860712 endingPage "4068" @default.
• W196860712 startingPage "4059" @default.
• W196860712 abstract "Ce1−xSnxO2 (x = 0.1−0.5) solid solution and its Pd substituted analogue have been prepared by a single step solution combustion method using tin oxalate precursor. The compounds were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and H2/temperature programmed redution (TPR) studies. The cubic fluorite structure remained intact up to 50% of Sn substitution in CeO2, and the compounds were stable up to 700 °C. Oxygen storage capacity of Ce1−xSnxO2 was found to be much higher than that of Ce1−xZrxO2 due to accessible Ce4+/Ce3+ and Sn4+/Sn2+ redox couples at temperatures between 200 and 400 °C. Pd2+ ions in Ce0.78Sn0.2Pd0.02O2-δ are highly ionic, and the lattice oxygen of this catalyst is highly labile, leading to low temperature CO to CO2 conversion. The rate of CO oxidation was 2 μmol g−1 s−1 at 50 °C. NO reduction by CO with 70% N2 selectivity was observed at ∼200 °C and 100% N2 selectivity below 260 °C with 1000−5000 ppm NO. Thus, Pd2+ ion substituted Ce1−xSnxO2 is a superior catalyst compared to Pd2+ ions in CeO2, Ce1−xZrxO2, and Ce1−xTixO2 for low temperature exhaust applications due to the involvement of the Sn2+/Sn4+ redox couple along with Pd2+/Pd0 and Ce4+/Ce3+ couples." @default.
• W196860712 created "2016-06-24" @default.
• W196860712 creator A5007396011 @default.
• W196860712 creator A5010672605 @default.
• W196860712 creator A5018732064 @default.
• W196860712 creator A5056908964 @default.
• W196860712 creator A5090146054 @default.
• W196860712 date "2009-02-17" @default.
• W196860712 modified "2023-09-25" @default.
• W196860712 title "High Oxygen Storage Capacity and High Rates of CO Oxidation and NO Reduction Catalytic Properties of Ce_1−<i>x</i>Sn_<i>x</i>O₂ and Ce_0.78Sn_0.2Pd_0.02O_2-δ" @default.
• W196860712 cites W155312606 @default.
• W196860712 cites W1964587285 @default.
• W196860712 cites W1969231561 @default.
• W196860712 cites W1972547700 @default.
• W196860712 cites W1976616721 @default.
• W196860712 cites W1979669531 @default.
• W196860712 cites W1992214743 @default.
• W196860712 cites W1997139112 @default.
• W196860712 cites W2013192026 @default.
• W196860712 cites W2014638115 @default.
• W196860712 cites W2020745701 @default.
• W196860712 cites W2026189118 @default.
• W196860712 cites W2029415108 @default.
• W196860712 cites W2029687732 @default.
• W196860712 cites W2035683840 @default.
• W196860712 cites W2038045235 @default.
• W196860712 cites W2040737011 @default.
• W196860712 cites W2043892912 @default.
• W196860712 cites W2044997998 @default.
• W196860712 cites W2056479051 @default.
• W196860712 cites W2060528573 @default.
• W196860712 cites W2074052196 @default.
• W196860712 cites W2075914414 @default.
• W196860712 cites W2088966222 @default.
• W196860712 cites W2090360347 @default.
• W196860712 cites W2091844646 @default.
• W196860712 cites W2094487550 @default.
• W196860712 cites W2125190194 @default.
• W196860712 cites W2167590372 @default.
• W196860712 cites W2256583900 @default.
• W196860712 cites W2951561466 @default.
• W196860712 cites W29541979 @default.
• W196860712 cites W4292199627 @default.
• W196860712 cites W62506358 @default.
• W196860712 doi "https://doi.org/10.1021/jp8060569" @default.
• W196860712 hasPublicationYear "2009" @default.
• W196860712 type Work @default.
• W196860712 sameAs 196860712 @default.
• W196860712 citedByCount "146" @default.
• W196860712 countsByYear W1968607122012 @default.
• W196860712 countsByYear W1968607122013 @default.
• W196860712 countsByYear W1968607122014 @default.
• W196860712 countsByYear W1968607122015 @default.
• W196860712 countsByYear W1968607122016 @default.
• W196860712 countsByYear W1968607122017 @default.
• W196860712 countsByYear W1968607122018 @default.
• W196860712 countsByYear W1968607122019 @default.
• W196860712 countsByYear W1968607122020 @default.
• W196860712 countsByYear W1968607122021 @default.
• W196860712 countsByYear W1968607122022 @default.
• W196860712 countsByYear W1968607122023 @default.
• W196860712 crossrefType "journal-article" @default.
• W196860712 hasAuthorship W196860712A5007396011 @default.
• W196860712 hasAuthorship W196860712A5010672605 @default.
• W196860712 hasAuthorship W196860712A5018732064 @default.
• W196860712 hasAuthorship W196860712A5056908964 @default.
• W196860712 hasAuthorship W196860712A5090146054 @default.
• W196860712 hasConcept C118792377 @default.
• W196860712 hasConcept C127413603 @default.
• W196860712 hasConcept C138999460 @default.
• W196860712 hasConcept C145148216 @default.
• W196860712 hasConcept C161790260 @default.
• W196860712 hasConcept C175708663 @default.
• W196860712 hasConcept C178790620 @default.
• W196860712 hasConcept C179104552 @default.
• W196860712 hasConcept C185592680 @default.
• W196860712 hasConcept C2182769 @default.
• W196860712 hasConcept C2776351790 @default.
• W196860712 hasConcept C42360764 @default.
• W196860712 hasConcept C525849907 @default.
• W196860712 hasConcept C540031477 @default.
• W196860712 hasConcept C55493867 @default.
• W196860712 hasConcept C55904794 @default.
• W196860712 hasConceptScore W196860712C118792377 @default.
• W196860712 hasConceptScore W196860712C127413603 @default.
• W196860712 hasConceptScore W196860712C138999460 @default.
• W196860712 hasConceptScore W196860712C145148216 @default.
• W196860712 hasConceptScore W196860712C161790260 @default.
• W196860712 hasConceptScore W196860712C175708663 @default.
• W196860712 hasConceptScore W196860712C178790620 @default.
• W196860712 hasConceptScore W196860712C179104552 @default.
• W196860712 hasConceptScore W196860712C185592680 @default.
• W196860712 hasConceptScore W196860712C2182769 @default.
• W196860712 hasConceptScore W196860712C2776351790 @default.
• W196860712 hasConceptScore W196860712C42360764 @default.
• W196860712 hasConceptScore W196860712C525849907 @default.
• W196860712 hasConceptScore W196860712C540031477 @default.
• W196860712 hasConceptScore W196860712C55493867 @default.

• next