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- W1968619477 abstract "Abstract The excess volume V E at 303.15 K has been measured for 11 ( n -alkanenitrile + n -alkane) mixtures: C 2 H 5 CN + n -C 5 H 12 , + n -C 6 H 14 , + n -C 7 H 16 , and + n -C 8 H 18 ; n -C 3 H 7 CN + n -C 5 H 12 , + n -C 6 H 14 , + n -C 8 H 18 , + n -C 10 H 22 , + n -C 12 H 26 , and + n -C 14 H 30 ; and n -C 5 H 11 CN + n -C 6 H 14 . Three of the mixtures, (C 2 H 5 CN + n -C 5 H 12 ), ( n -C 3 H 7 CN + n -C 5 H 12 ), and ( n -C 5 H 11 CN + n -C 6 H 14 ), exhibit sign inversion with the negative portion of the V E isotherm occurring in nitrile-rich mixtures. For the remaining mixtures, V E is positive with a magnitude which increases with increasing alkane size and decreasing nitrile size in a fashion consistent with the diminished role of polarity in nitriles of large chain length." @default.
- W1968619477 created "2016-06-24" @default.
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- W1968619477 date "1980-08-01" @default.
- W1968619477 modified "2023-09-27" @default.
- W1968619477 title "Excess functions for (n-alkanenitrile + n-alkane) liquid mixtures I. Excess volumes at 303.15 K for propanenitrile, n-butanenitrile, and n-hexanenitrile with some C5 to C14 n-alkanes" @default.
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