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- W1968629526 abstract "Abstract The effect of beta-cyclodextrin (β-CD) on the peak height and voltage of the polarographic reduction of several esters of hydroxybenzoic acid has been investigated. Complexation with β-CD decreased both the amount of current conducted upon reduction and the half-wave potential of that reduction for each of the esters of hydroxybenzoic acid. This fall in conducted current resulted from the decreased diffusion rate of the ester when complexed with β-CD as compared to the ester alone. The half-wave potentials of the reductions became more negative in the presence of β-CD. The change in potential was in the rank order ethyl > propyl > butyl. This was a result of the electron redistribution occurring in the presence of β-CD due to the formation of inclusion complexes, and reflected the tendency of these esters to complex with β-CD. These results suggest that polarography is suitable for studying the inclusion complexation phenomenon of β-CD with electroactive molecules in aqueous solution and may prove to be a powerful technique in further elucidating the nature of the inclusion complex." @default.
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- W1968629526 date "1986-11-01" @default.
- W1968629526 modified "2023-09-27" @default.
- W1968629526 title "Polarographic detection of beta-cyclodextrin inclusion complexes" @default.
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- W1968629526 doi "https://doi.org/10.1016/0378-5173(86)90044-x" @default.
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