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- W1968651074 abstract "The first example of a palladium-catalyzed highly enantioselective synthesis of α-tertiary hydroxyaldehydes is described using allylic alkylation of siloxy enol carbonates. The reaction proceeds under mild conditions and the substrates can be readily made from α-halo or α-hydroxy ketones. The scope is also broad, encompassing various protecting groups and substituents on the enol ether with excellent yields and enantioselectivities. The synthetic utility of the methodology is demonstrated by converting one product into a key precursor for the synthesis of the anticholinergic drug (S)-oxybutynin." @default.
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- W1968651074 date "2007-04-01" @default.
- W1968651074 modified "2023-10-18" @default.
- W1968651074 title "Palladium-Catalyzed Asymmetric Allylic Alkylation of Enolates" @default.
- W1968651074 doi "https://doi.org/10.1055/s-2007-968339" @default.
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