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- W1968651255 abstract "The interaction of H2 and N2 on extremely clean iron films was investigated by mass spectrometric measurements of displacement, thermal desorption, isotopic equilibration, and by measurements of electrical resistance. The adsorption of N2 on iron films partially covered with H2, the adsorption of H2 on iron films partially covered with N2, and the alternating adsorption of N2 and H2 were studied. The results were obtained in the temperature range from 77 to 400 K and at pressures up to 5 × 10−4 Torr. Nitrogen does not displace hydrogen from the iron surface; it is physisorbed on a monolayer of chemisorbed hydrogen. Hydrogen displaces nitrogen from the iron surface. The kinetics of these reactions are discussed. It was found that the isotopic equilibrium between 14N2 and 15N2 was not established even when nitrogen was adsorbed on iron in the presence of hydrogen. Thermal desorption studies produced no evidence for the formation of NH adducts." @default.
- W1968651255 created "2016-06-24" @default.
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- W1968651255 date "1976-07-01" @default.
- W1968651255 modified "2023-10-04" @default.
- W1968651255 title "The interaction of hydrogen and nitrogen on polycrystalline iron films at low pressures and at low temperatures" @default.
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- W1968651255 doi "https://doi.org/10.1016/0021-9517(76)90383-3" @default.
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