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• W1968652307 abstract "Isolated rust layers have been investigated by electrochemical methods to find out whether their reduction and re-oxidation can affect the atmospheric corrosion of iron. At potentials below 0 mV, first a thin Fe2+-containing surface layer is formed on top of the γ-FeOOH. This reduced surface layer can dissolve into the cell electrolyte at acid pH, or at lower potentials the Fe2+-ions can react with γ-FeOOH to Fe3O4. The formation of magnetite could be followed by in-situ magnetic measurements. The reduced surface layer can easily be oxidized back to γ-FeOOH, magnetite can partly be oxidized to γ-Fe2O3." @default.
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• W1968652307 date "1983-01-01" @default.
• W1968652307 modified "2023-10-16" @default.
• W1968652307 title "An electrochemical study of phase-transitions in rust layers" @default.
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• W1968652307 doi "https://doi.org/10.1016/0010-938x(83)90024-0" @default.
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