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• W1968659822 abstract "1,2-Benzophenoxazine-7-one (BPO) was absorbed on graphite to give a chemically modified electrode. The electrochemical redox reactions of BPO itself are fairly reversible at coverages less than 2 × 10−9 mol cm−2 with an E°′ of −210 mV (vs. SCE) at pH 7.0. The E°′ decreased 60 mV per pH unit from pH 1 to 11. The adsorbed BPO mediated electron transfer in the electrocatalytic oxidation of the dihydronicotinamide adenine dinucleotide (NADH). The kinetic reaction was studied with a rotating disk electrode modified with BPO for different coenzyme concentrations and pHs. The formation of a charge-transfer complex between NADH and the mediator was indicated. The rate of reaction increased as the pH decreased; the slope of a log k+2 vs. pH plot was −0.55, indicating a complex proton dependence. A reaction scheme with two parallel paths is discussed." @default.
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• W1968659822 date "1985-12-01" @default.
• W1968659822 modified "2023-10-18" @default.
• W1968659822 title "A kinetic study of the reaction between dihydronicotinamide adenine dinucleotide (NADH) and an electrode modified by adsorption of 1,2-benzophenoxazine-7-one" @default.
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• W1968659822 doi "https://doi.org/10.1016/0022-0728(85)85082-8" @default.
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