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• W1968670540 abstract "Aminoalkyl radicals, such as Et2NCHCH3, have low oxidation potentials and are therefore powerful reducing agents. We have found that Et2NCHCH3 reacts with CCl4 and CBr4 in di-tert-butyl peroxide with bimolecular rate constants (measured by LFP) close, or equal, to the diffusion-controlled limit. For the less reactive halide, CH2Br2, the reaction rate is increased substantially by the addition of acetonitrile as a co-solvent. It is tentatively concluded that these reactions occur by electron-transfer from the aminoalkyl to the organohalide with formation of the iminium ion, Et2N+CHCH3 (NMR detection), halide ion and a halomethyl radical, e.g., CCl3 and CHCl2 (ESR, spin-trapping detection)." @default.
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• W1968670540 date "2011-07-01" @default.
• W1968670540 modified "2023-10-14" @default.
• W1968670540 title "Reaction between aminoalkyl radicals and akyl halides: Dehalogenation by electron transfer?" @default.
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• W1968670540 doi "https://doi.org/10.1016/j.cplett.2011.05.055" @default.
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