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- W1968682114 abstract "Photoemission data from cosputtered films of binary alloys of Ru, Rh, Pd, Ir, Pt and Au with Mg show that the transition metal (TM) d band narrows as the TM concentration is reduced, reaching a minimum after which the intensity decreases but the width remains constant. The continuity of binding energy, spin-orbit splitting and width of the resulting d states suggests a high level of d-band occupancy in all cases. LMTO bandstructure calculations for pure TM and ordered intermetallic compounds of the form MgTM and Mg3TM also show narrowing of the d bands, with binding energies and widths which indicate that they are fully, or nearly fully occupied in all cases where the TM is dilute. The authors suggest that the additional d intensity results from a spread of the TM d wavefunctions on to the surrounding Mg sites, allowing high d-band occupancy whilst preserving charge neutrality." @default.
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- W1968682114 date "1991-11-11" @default.
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- W1968682114 title "High d-band occupancy in alloys of Mg with some 4d and 5d transition metals: a photoemission study" @default.
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- W1968682114 doi "https://doi.org/10.1088/0953-8984/3/45/009" @default.
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