FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1968687803> ?p ?o ?g. }

• W1968687803 endingPage "771" @default.
• W1968687803 startingPage "764" @default.
• W1968687803 abstract "In this work, a large-volume on-column injection method for the analysis of 21 organochlorine pesticides, including HCH isomers, DDT derivatives and cyclodiene derivatives, was optimized. The solvent selected to carry out the study was ethyl acetate and the injection volume was 100 μl. Some factors were introduced in a Plackett–Burman design to determine their influence in the vaporization efficiency. The significant factors were then studied by a univariate procedure and sorted according to their importance on the response. The effect of the injection conditions on the peak resolution was also noted. The conditions selected according to sensitivity and resolution were: initial oven temperature 75 °C, injection speed 20 μl s−1, solvent vapor exit (SVE) valve closure time 60 s, initial pressure 100 kPa and isothermal oven time 1 min. Analytical characteristics expressed in terms of precision, linear range, and limit of detection have been determined and compared with those obtained by splitless injection. The degradation of endrin and p,p′-DDT thermolabile pesticides was evaluated for both injection techniques. Finally the developed method was successfully applied to the ultratrace analysis of pesticides in natural waters. With this purpose a micro liquid–liquid extraction method using 2 ml of ethyl acetate to extract 10 ml of water sample was proposed. Recoveries between 69 and 107% were obtained with a very good precision (0.2–1.3%) for the studied pesticides, except for p,p′-DDD. Detection limits between 0.3 and 25 ng l−1, which fulfill the limits established by the new water directive 2008/105/EC, were achieved. The MLLE method was compared with the SPE method by the analysis of some water samples using both procedures, and good concordance was obtained." @default.
• W1968687803 created "2016-06-24" @default.
• W1968687803 creator A5005319169 @default.
• W1968687803 creator A5025008175 @default.
• W1968687803 creator A5034752100 @default.
• W1968687803 creator A5045588707 @default.
• W1968687803 creator A5064050041 @default.
• W1968687803 creator A5079565842 @default.
• W1968687803 creator A5091594239 @default.
• W1968687803 date "2009-05-15" @default.
• W1968687803 modified "2023-10-17" @default.
• W1968687803 title "A study of large-volume on-column injection GC–ECD for the ultratrace analysis of organochlorine pesticides in water" @default.
• W1968687803 cites W1980045267 @default.
• W1968687803 cites W1985120379 @default.
• W1968687803 cites W1989233225 @default.
• W1968687803 cites W1998617780 @default.
• W1968687803 cites W1999316688 @default.
• W1968687803 cites W2000046139 @default.
• W1968687803 cites W2005588696 @default.
• W1968687803 cites W2005867815 @default.
• W1968687803 cites W2007551832 @default.
• W1968687803 cites W2018234065 @default.
• W1968687803 cites W2019462809 @default.
• W1968687803 cites W2022650889 @default.
• W1968687803 cites W2029277701 @default.
• W1968687803 cites W2042507798 @default.
• W1968687803 cites W2055582933 @default.
• W1968687803 cites W2063158383 @default.
• W1968687803 cites W2076831484 @default.
• W1968687803 cites W2079468499 @default.
• W1968687803 cites W2092387974 @default.
• W1968687803 cites W2113839863 @default.
• W1968687803 cites W3024563727 @default.
• W1968687803 cites W36579546 @default.
• W1968687803 cites W73770700 @default.
• W1968687803 doi "https://doi.org/10.1016/j.talanta.2008.12.043" @default.
• W1968687803 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19269426" @default.
• W1968687803 hasPublicationYear "2009" @default.
• W1968687803 type Work @default.
• W1968687803 sameAs 1968687803 @default.
• W1968687803 citedByCount "14" @default.
• W1968687803 countsByYear W19686878032012 @default.
• W1968687803 countsByYear W19686878032013 @default.
• W1968687803 countsByYear W19686878032015 @default.
• W1968687803 countsByYear W19686878032018 @default.
• W1968687803 countsByYear W19686878032019 @default.
• W1968687803 countsByYear W19686878032020 @default.
• W1968687803 countsByYear W19686878032021 @default.
• W1968687803 countsByYear W19686878032023 @default.
• W1968687803 crossrefType "journal-article" @default.
• W1968687803 hasAuthorship W1968687803A5005319169 @default.
• W1968687803 hasAuthorship W1968687803A5025008175 @default.
• W1968687803 hasAuthorship W1968687803A5034752100 @default.
• W1968687803 hasAuthorship W1968687803A5045588707 @default.
• W1968687803 hasAuthorship W1968687803A5064050041 @default.
• W1968687803 hasAuthorship W1968687803A5079565842 @default.
• W1968687803 hasAuthorship W1968687803A5091594239 @default.
• W1968687803 hasConcept C113196181 @default.
• W1968687803 hasConcept C119128265 @default.
• W1968687803 hasConcept C121332964 @default.
• W1968687803 hasConcept C138268822 @default.
• W1968687803 hasConcept C154945302 @default.
• W1968687803 hasConcept C161176658 @default.
• W1968687803 hasConcept C178790620 @default.
• W1968687803 hasConcept C185592680 @default.
• W1968687803 hasConcept C195801359 @default.
• W1968687803 hasConcept C20556612 @default.
• W1968687803 hasConcept C2779858419 @default.
• W1968687803 hasConcept C2780471494 @default.
• W1968687803 hasConcept C41008148 @default.
• W1968687803 hasConcept C43617362 @default.
• W1968687803 hasConcept C4725764 @default.
• W1968687803 hasConcept C62520636 @default.
• W1968687803 hasConcept C6557445 @default.
• W1968687803 hasConcept C86803240 @default.
• W1968687803 hasConceptScore W1968687803C113196181 @default.
• W1968687803 hasConceptScore W1968687803C119128265 @default.
• W1968687803 hasConceptScore W1968687803C121332964 @default.
• W1968687803 hasConceptScore W1968687803C138268822 @default.
• W1968687803 hasConceptScore W1968687803C154945302 @default.
• W1968687803 hasConceptScore W1968687803C161176658 @default.
• W1968687803 hasConceptScore W1968687803C178790620 @default.
• W1968687803 hasConceptScore W1968687803C185592680 @default.
• W1968687803 hasConceptScore W1968687803C195801359 @default.
• W1968687803 hasConceptScore W1968687803C20556612 @default.
• W1968687803 hasConceptScore W1968687803C2779858419 @default.
• W1968687803 hasConceptScore W1968687803C2780471494 @default.
• W1968687803 hasConceptScore W1968687803C41008148 @default.
• W1968687803 hasConceptScore W1968687803C43617362 @default.
• W1968687803 hasConceptScore W1968687803C4725764 @default.
• W1968687803 hasConceptScore W1968687803C62520636 @default.
• W1968687803 hasConceptScore W1968687803C6557445 @default.
• W1968687803 hasConceptScore W1968687803C86803240 @default.
• W1968687803 hasIssue "3" @default.
• W1968687803 hasLocation W19686878031 @default.
• W1968687803 hasLocation W19686878032 @default.
• W1968687803 hasOpenAccess W1968687803 @default.
• W1968687803 hasPrimaryLocation W19686878031 @default.

• next