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- W1968694734 abstract "Neue Dithia[3.3]metacyclophane (Tab.2) wurden synthetisiert und ihre Konformation zugeordnet. Ihre Abhängigkeit von extra- und intraanularen Substituenten, insbesondere Methoxy-, Amino-und Phenyl-Gruppen wird erörtert. Die Barrieren der thermischen Umlagerung von syn-22 und 24 in die anti-Konformeren (A) wurden kinetisch zu 135 kJ/mol und 131kJ/mol bestimmt. Das intraanular azo-substituierte [3.2.3](1,2,3)Phan 32 mit fixierter syn-Konformation wird beschrieben. syn/anti-Conformers and-Rearrangements of Intra- and Extraanularly Substituted Dithia[3.3]metacyclophanes New dithia[3.3]metacyclophanes (Table 2) have been synthesized and their conformations determined. The dependence of extra-and intraanular substituents, especially methoxy, amino and phenyl groups, are discussed. The barriers of the thermal rearrangement of syn-22 and -24 to the anti-conformers A have been measured kinetically (135 and 131 kJ/mol, resp.). The intraanularly azo-substituted [3.2.3](1,2,3)phane 32 is described." @default.
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- W1968694734 date "1981-03-01" @default.
- W1968694734 modified "2023-10-18" @default.
- W1968694734 title "<i>syn</i> / <i>anti</i> ‐Konformere und‐Umlagerungen intra‐und extraanular substituierter Dithia [3.3]metacyclophane" @default.
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- W1968694734 doi "https://doi.org/10.1002/cber.19811140323" @default.
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