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- W1968698863 abstract "Subjection of N-methyl carbazolone allyl carbonates bearing a propargyl side chain to Pd0 catalysis leads to the formation of enantioenriched γ-lactones, rather than the expected products of decarboxylative allylation. This side reaction has not been observed with the enantioselective decarboxylative allylation of related β-ketoesters, and provides evidence for a mechanism involving turnover limiting decarboxylation from the palladium carboxylate resting state. Following lactonisation, the Pd0 catalyst is regenerated by PdII reductive alkyne coupling." @default.
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- W1968698863 date "2014-01-01" @default.
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- W1968698863 title "Enantioselective Pd-Catalysed Deallylative γ-Lactonisation of Propargyl Carbazolone Allyl Carbonates: Mechanistic Insight into their Decarboxylative Allylation" @default.
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- W1968698863 doi "https://doi.org/10.1071/ch14211" @default.
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