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- W1968699123 abstract "Abstract Two new cobalt phosphonates, [enH 2 ] 0.5 [Co(HL)(H 2 O)] · H 2 O (1) and [Co 2 (HL)(H 2 L) 2 ] · 2NH(CH 3 ) 2 · 3H 2 O (2) (H 3 L = 2-hydroxyphosphonoacetic acid; en = ethylenediamine), have been synthesized under hydrothermal conditions and structurally characterized by X-ray single-crystal diffraction, X-ray powder diffraction, infrared spectroscopy, elemental analysis and thermogravimetric analysis. For compound 1 , Co(II) atoms are octahedrally coordinated. The CoO 6 octahedra and CPO 3 tetrahedra are linked by HL 2 − into a 2D layered structure in the bc -plane. The ethylenediamine molecules and solvate water molecules are located between two adjacent layers. The structure of compound 2 composed of Co1O 6 and Co2O 6 octahedra via bridging phosphonate ligands leads to a 2D layered structure with one-dimensional channel system along c -axis direction. The dimethylamine molecules and solvate water molecules are located between two adjacent layers. The surface photovoltage properties of compounds 1 and 2 have also been studied." @default.
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- W1968699123 date "2014-02-01" @default.
- W1968699123 modified "2023-10-17" @default.
- W1968699123 title "Synthesis, structure, and surface photovoltage property of two new cobalt (II) phosphonates with 2D layered structure" @default.
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- W1968699123 doi "https://doi.org/10.1016/j.inoche.2013.12.018" @default.
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