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- W1968704773 abstract "We report results from a molecular simulation study of the structure and dynamics of water near single carbohydrate molecules (glucose, trehalose, and sucrose) at 0 and 30 degrees C. The presence of a carbohydrate molecule has a number of significant effects on the microscopic water structure and dynamics. All three carbohydrates disrupt the tetrahedral arrangement of proximal water molecules and restrict their translational and rotational mobility. These destructuring effects and slow dynamics are the result of steric constraints imposed by the carbohydrate molecule and of the ability of a carbohydrate to form stable H bonds with water, respectively. The carbohydrates induce a pronounced decoupling between translational and rotational motions of proximal water molecules." @default.
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- W1968704773 date "2005-05-22" @default.
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- W1968704773 title "A computational study of hydration, solution structure, and dynamics in dilute carbohydrate solutions" @default.
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- W1968704773 doi "https://doi.org/10.1063/1.1917745" @default.
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