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- W1968763973 abstract "The reaction of (L2MnIII2(µ-O)(µ-MeCO2)2](CIO4)2 with Na2HPO4, (NH4)3VO4, or Na2HAsO4 in aqueous solution (pH ca. 9) in the presence of air yields, upon addition of NaBr, deep red crystals of [L3MnIV3(µ2-O)3(µ3-XO4)]Br3(X = P, As, or VV; L = 1,4,7-triazacyclononane); characterization of the µ-phosphato complex by X-ray crystallography showed the presence of discrete trimeric cations [L3MnIV3(µ-O)3(µ-PO4)]3+ where three MnIV centres are in a distorted octahedral fac-N3O3 donor set connected by three µ2-oxo bridges and a µ3-PO4 bridge." @default.
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- W1968763973 date "1988-01-01" @default.
- W1968763973 modified "2023-09-27" @default.
- W1968763973 title "Synthesis of novel trimeric µ-oxo-bridged manganese(<scp>IV</scp>) complexes: [L<sub>3</sub>Mn<sub>3</sub><sup>IV</sup>(µ<sub>2</sub>-O)<sub>3</sub>(µ<sub>3</sub>-XO<sub>4</sub>)]Br<sub>3</sub>(X = P, As, or V<sup>V</sup>; L = 1,4,7-triazacyclononane)" @default.
- W1968763973 doi "https://doi.org/10.1039/c39880001145" @default.
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